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On April 1, 1948 a paper was published in the Physical Review by Alpher, Bethe, and Gamow, entitled “The Origin of Chemical Elements.” The authors’ names were a bit of a joke (Hans Bethe hadn’t really contributed to the work), but the paper contains a significant scientific discovery. Ralph Alpher and George Gamow explained how the extreme conditions shortly after the big bang could explain the observed abundances of the most common elements in the universe.

They started by imagining the early stage of the universe as an extremely hot dense gas of neutrons, (which they called “ylem,” after a medieval word for matter). As the universe expanded, the hot compressed neutrons would decay into a mixture of protons and electrons and neutrinos. Then the protons would capture some of the remaining neutrons to form deuterium. Further neutron capture would build up heavier and heavier atomic nuclei. The process would continue as the universe expanded until it was too cool for further reactions to take place.

Left to right: Ralph Alpher, George Gamow, and Hans Bethe.

Alpher’s calculations of nuclear processes used some of the first electronic digital computers, which had been developed during World War II. He was also able to use new data on nuclear reaction cross sections that had become available after the war ended.

The calculations agreed with the known abundance of helium. Pleased with their result, Alpher and Gamow submitted a brief communication to the Physical Review, titled “The Origin of Chemical Elements.” They celebrated with a bottle of liqueur, which Gamow relabeled “ylem.”

Gamow, who was known for his sense of humor, saw that the paper they had submitted to Phys. Rev. was to appear on April 1, 1948. He added the name of his friend Hans Bethe, who was known for work on nuclear reactions in stars, among other things, to the paper, so the authors would be Alpher, Bethe, and Gamow, a pun on the first three letters of the Greek alphabet.

The theory originally proposed that all atomic nuclei are produced by the successive capture of neutrons, one mass unit at a time. However, later study challenged the universality of the successive capture theory. No element was found to have a stable isotope with an atomic mass of five or eight. Physicists soon noticed that these mass gaps would hinder the production of elements beyond helium. Just as it's impossible to climb a staircase one step at a time when one of the steps is missing, this discovery meant that the successive capture theory could not account for higher elements.

It was eventually recognized that most of the heavy elements observed in the present universe are the result of stellar nucleosynthesis in stars, a theory first suggested by Arthur Stanley Eddington, given credence by Hans Bethe, and quantitatively developed by Fred Hoyle and a number of other scientists.

However, the Alpher–Bethe–Gamow theory does correctly explain the relative abundances of the isotopes of hydrogen and helium. Taken together, these account for more than 99% of the baryonic mass of the universe. Today, nucleosynthesis is widely considered to have taken place in two stages: formation of hydrogen and helium according to the Alpher–Bethe–Gamow theory, and stellar nucleosynthesis of higher elements according to Bethe and Hoyle's later theories.

Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis, arch(a)eonucleosynthesis, archonucleosynthesis, protonucleosynthesis and pal(a)eonucleosynthesis) refers to the production of nuclei other than those of the lightest isotope of hydrogen (hydrogen-1, 1H, having a single proton as a nucleus) during the early phases of the Universe. Primordial nucleosynthesis is believed by most cosmologists to have taken place in the interval from roughly 10 seconds to 20 minutes after the Big Bang, and is calculated to be responsible for the formation of most of the universe's helium as the isotope helium-4 (4He), along with small amounts of the hydrogen isotope deuterium (2H or D), the helium isotope helium-3 (3He), and a very small amount of the lithium isotope lithium-7 (7Li). In addition to these stable nuclei, two unstable or radioactiveisotopes were also produced: the heavy hydrogen isotope tritium (3H or T); and the beryllium isotope beryllium-7 (7Be); but these unstable isotopes later decayed into 3He and 7Li, as above.

Essentially all of the elements that are heavier than lithium were created much later, by stellar nucleosynthesis in evolving and exploding stars.

Characteristics

There are several important characteristics of Big Bang nucleosynthesis (BBN):

  • The initial conditions (neutron-proton ratio) were set in the first second after the Big Bang.
  • The universe was very close to homogeneous at this time, and strongly radiation-dominated.
  • The fusion of nuclei occurred between roughly 10 seconds to 20 minutes after the Big Bang; this corresponds to the temperature range when the universe was cool enough for deuterium to survive, but hot and dense enough for fusion reactions to occur at a significant rate.
  • It was widespread, encompassing the entire observable universe.

The key parameter which allows one to calculate the effects of BBN is the baryon/photon number ratio, which is a small number of order 6 × 10−10. This parameter corresponds to the baryon density and controls the rate at which nucleons collide and react; from this it is possible to calculate element abundances after nucleosynthesis ends. Although the baryon per photon ratio is important in determining element abundances, the precise value makes little difference to the overall picture. Without major changes to the Big Bang theory itself, BBN will result in mass abundances of about 75% of hydrogen-1, about 25% helium-4, about 0.01% of deuterium and helium-3, trace amounts (on the order of 10−10) of lithium, and negligible heavier elements. That the observed abundances in the universe are generally consistent with these abundance numbers is considered strong evidence for the Big Bang theory.

In this field, for historical reasons it is customary to quote the helium-4 fraction by mass, symbol Y, so that 25% helium-4 means that helium-4 atoms account for 25% of the mass, but less than 8% of the nuclei would be helium-4 nuclei. Other (trace) nuclei are usually expressed as number ratios to hydrogen.

Sequence

Big Bang nucleosynthesis began roughly 10 seconds after the big bang, when the universe had cooled sufficiently to allow deuterium nuclei to survive disruption by high-energy photons. (Note that the neutron-proton freeze-out time was earlier). This time is essentially independent of dark matter content, since the universe was highly radiation dominated until much later, and this dominant component controls the temperature/time relation. At this time there were about six protons for every neutron, but a small fraction of the neutrons decay before fusing in the next few hundred seconds, so at the end of nucleosynthesis there are about seven protons to every neutron, and almost all the neutrons are in Helium-4 nuclei. The sequence of these reaction chains is shown on the image.


The main nuclear reaction chains for Big Bang nucleosynthesis.

One feature of BBN is that the physical laws and constants that govern the behavior of matter at these energies are very well understood, and hence BBN lacks some of the speculative uncertainties that characterize earlier periods in the life of the universe. Another feature is that the process of nucleosynthesis is determined by conditions at the start of this phase of the life of the universe, and proceeds independently of what happened before.

As the universe expands, it cools. Free neutrons are less stable than helium nuclei, and the protons and neutrons have a strong tendency to form helium-4. However, forming helium-4 requires the intermediate step of forming deuterium. Before nucleosynthesis began, the temperature was high enough for many photons to have energy greater than the binding energy of deuterium; therefore any deuterium that was formed was immediately destroyed (a situation known as the deuterium bottleneck). Hence, the formation of helium-4 is delayed until the universe became cool enough for deuterium to survive (at about T = 0.1 MeV); after which there was a sudden burst of element formation. However, very shortly thereafter, around twenty minutes after the Big Bang, the temperature and density became too low for any significant fusion to occur. At this point, the elemental abundances were nearly fixed, and the only changes were the result of the radioactive decay of the two major unstable products of BBN, tritium and beryllium-7.

Heavy elements

Big Bang nucleosynthesis produced very few nuclei of elements heavier than lithium due to a bottleneck: the absence of a stable nucleus with 8 or 5 nucleons. This deficit of larger atoms also limited the amounts of lithium-7 produced during BBN. In stars, the bottleneck is passed by triple collisions of helium-4 nuclei, producing carbon (the triple-alpha process). However, this process is very slow and requires much higher densities, taking tens of thousands of years to convert a significant amount of helium to carbon in stars, and therefore it made a negligible contribution in the minutes following the Big Bang.

The predicted abundance of CNO isotopes produced in Big Bang nucleosynthesis is expected to be on the order of 10−15 that of H, making them essentially undetectable and negligible. Indeed, none of these primordial isotopes of the elements from lithium to oxygen have yet been detected, although those of beryllium and boron may be able to be detected in the future. So far, the only stable nuclides known experimentally to have been made before or during Big Bang nucleosynthesis are protium, deuterium, helium-3, helium-4, and lithium-7.


A version of the periodic table indicating the origins – including big bang nucleosynthesis – of the elements. All elements above 103 (lawrencium) are also manmade and are not included.

Helium-4

Big Bang nucleosynthesis predicts a primordial abundance of about 25% helium-4 by mass, irrespective of the initial conditions of the universe. As long as the universe was hot enough for protons and neutrons to transform into each other easily, their ratio, determined solely by their relative masses, was about 1 neutron to 7 protons (allowing for some decay of neutrons into protons). Once it was cool enough, the neutrons quickly bound with an equal number of protons to form first deuterium, then helium-4. Helium-4 is very stable and is nearly the end of this chain if it runs for only a short time, since helium neither decays nor combines easily to form heavier nuclei (since there are no stable nuclei with mass numbers of 5 or 8, helium does not combine easily with either protons, or with itself). Once temperatures are lowered, out of every 16 nucleons (2 neutrons and 14 protons), 4 of these (25% of the total particles and total mass) combine quickly into one helium-4 nucleus. This produces one helium for every 12 hydrogens, resulting in a universe that is a little over 8% helium by number of atoms, and 25% helium by mass.

One analogy is to think of helium-4 as ash, and the amount of ash that one forms when one completely burns a piece of wood is insensitive to how one burns it. The resort to the BBN theory of the helium-4 abundance is necessary as there is far more helium-4 in the universe than can be explained by stellar nucleosynthesis. In addition, it provides an important test for the Big Bang theory. If the observed helium abundance is significantly different from 25%, then this would pose a serious challenge to the theory. This would particularly be the case if the early helium-4 abundance was much smaller than 25% because it is hard to destroy helium-4. For a few years during the mid-1990s, observations suggested that this might be the case, causing astrophysicists to talk about a Big Bang nucleosynthetic crisis, but further observations were consistent with the Big Bang theory.

Deuterium

Deuterium is in some ways the opposite of helium-4, in that while helium-4 is very stable and difficult to destroy, deuterium is only marginally stable and easy to destroy. The temperatures, time, and densities were sufficient to combine a substantial fraction of the deuterium nuclei to form helium-4 but insufficient to carry the process further using helium-4 in the next fusion step. BBN did not convert all of the deuterium in the universe to helium-4 due to the expansion that cooled the universe and reduced the density, and so cut that conversion short before it could proceed any further. One consequence of this is that, unlike helium-4, the amount of deuterium is very sensitive to initial conditions. The denser the initial universe was, the more deuterium would be converted to helium-4 before time ran out, and the less deuterium would remain.

There are no known post-Big Bang processes which can produce significant amounts of deuterium. Hence observations about deuterium abundance suggest that the universe is not infinitely old, which is in accordance with the Big Bang theory.

During the 1970s, there were major efforts to find processes that could produce deuterium, but those revealed ways of producing isotopes other than deuterium. The problem was that while the concentration of deuterium in the universe is consistent with the Big Bang model as a whole, it is too high to be consistent with a model that presumes that most of the universe is composed of protons and neutrons. If one assumes that all of the universe consists of protons and neutrons, the density of the universe is such that much of the currently observed deuterium would have been burned into helium-4. The standard explanation now used for the abundance of deuterium is that the universe does not consist mostly of baryons, but that non-baryonic matter (also known as dark matter) makes up most of the mass of the universe.[citation needed] This explanation is also consistent with calculations that show that a universe made mostly of protons and neutrons would be far more clumpy than is observed.

It is very hard to come up with another process that would produce deuterium other than by nuclear fusion. Such a process would require that the temperature be hot enough to produce deuterium, but not hot enough to produce helium-4, and that this process should immediately cool to non-nuclear temperatures after no more than a few minutes. It would also be necessary for the deuterium to be swept away before it reoccurs.

Producing deuterium by fission is also difficult. The problem here again is that deuterium is very unlikely due to nuclear processes, and that collisions between atomic nuclei are likely to result either in the fusion of the nuclei, or in the release of free neutrons or alpha particles. During the 1970s, cosmic ray spallation was proposed as a source of deuterium. That theory failed to account for the abundance of deuterium, but led to explanations of the source of other light elements.

Measurements and status of theory

The theory of BBN gives a detailed mathematical description of the production of the light "elements" deuterium, helium-3, helium-4, and lithium-7. Specifically, the theory yields precise quantitative predictions for the mixture of these elements, that is, the primordial abundances at the end of the big-bang.

In order to test these predictions, it is necessary to reconstruct the primordial abundances as faithfully as possible, for instance by observing astronomical objects in which very little stellar nucleosynthesis has taken place (such as certain dwarf galaxies) or by observing objects that are very far away, and thus can be seen in a very early stage of their evolution (such as distant quasars).

As noted above, in the standard picture of BBN, all of the light element abundances depend on the amount of ordinary matter (baryons) relative to radiation (photons). Since the universe is presumed to be homogeneous, it has one unique value of the baryon-to-photon ratio. For a long time, this meant that to test BBN theory against observations one had to ask: can all of the light element observations be explained with a single value of the baryon-to-photon ratio? Or more precisely, allowing for the finite precision of both the predictions and the observations, one asks: is there some range of baryon-to-photon values which can account for all of the observations?

More recently, the question has changed: Precision observations of the cosmic microwave background radiation with the Wilkinson Microwave Anisotropy Probe (WMAP) and Planck give an independent value for the baryon-to-photon ratio. Using this value, are the BBN predictions for the abundances of light elements in agreement with the observations?

The present measurement of helium-4 indicates good agreement, and yet better agreement for helium-3. But for lithium-7, there is a significant discrepancy between BBN and WMAP/Planck, and the abundance derived from Population II stars. The discrepancy is a factor of 2.4―4.3 below the theoretically predicted value and is considered a problem for the original models, that have resulted in revised calculations of the standard BBN based on new nuclear data, and to various reevaluation proposals for primordial proton-proton nuclear reactions, especially the abundances of 

7Be + n → 7Li + p, versus 7Be + 2H → 8Be + p.

Abundances of the chemical elements in the Solar System.

Hydrogen and helium are most common, residuals within the paradigm of the Big Bang. The next three elements (Li, Be, B) are rare because they are poorly synthesized in the Big Bang and also in stars. The two general trends in the remaining stellar-produced elements are: 

  • (1) an alternation of abundance of elements according to whether they have even or odd atomic numbers, and 
  • (2) a general decrease in abundance, as elements become heavier. Within this trend is a peak at abundances of iron and nickel, which is especially visible on a logarithmic graph spanning fewer powers of ten, say between logA=2 (A=100) and logA=6 (A=1,000,000).

REFERENCES

American Physical Society. Available in: https://www.aps.org/publications/apsnews/200804/physicshistory.cfm. Access in: 26/11/2018.

Cornell University. Available in: http://hosting.astro.cornell.edu/academics/courses/astro201/primordnuc.htm. Access in: 26/11/2018.

Cornell University. Available in: https://arxiv.org/abs/1707.01004. Access in: 26/11/2018.

Wikipedia. Available in: https://en.wikipedia.org/wiki/Big_Bang_nucleosynthesis. Access: 26/11/2018.

Wikipedia. Available in: https://en.wikipedia.org/wiki/Alpher%E2%80%93Bethe%E2%80%93Gamow_paper. Access: 26/11/2018.

Wikipedia. Available in: https://en.wikipedia.org/wiki/Nucleosynthesis. Access: 26/11/2018.

 
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